Catalytic properties of Cr-containing heteropolytungstates in H2O2 participated reactions: H2O2 decomposition and oxidation of unsaturated hydrocarbons with H2O2
Author:
Publisher
Elsevier BV
Subject
Physical and Theoretical Chemistry,Process Chemistry and Technology,Catalysis
Reference22 articles.
1. Sustained epoxidation of olefins by oxygen donors catalyzed by transition metal-substituted polyoxometalates, oxidatively resistant inorganic analogs of metalloporphyrins
2. Highly oxidation resistant inorganic-porphyrin analog polyoxometalate oxidation catalysts. 1. The synthesis and characterization of aqueous-soluble potassium salts of .alpha.2-P2W17O61(Mn+.cntdot.OH2)(n-10) and organic solvent soluble tetra-n-butylammonium salts of .alpha.2-P2W17O61(Mn+.cntdot.Br)(n-11) (M = Mn3+,Fe3+,Co2+,Ni2+,Cu2+)
3. Highly oxidation resistant inorganic-porphyrin analog polyoxometalate oxidation catalysts. 2. Catalysis of olefin epoxidation and aliphatic and aromatic hydroxylations starting from .alpha.2-P2W17O61(Mn+.cntdot.Br)(n-11) (Mn+ = Mn3+,Fe3+,Co2+,Ni2+,Cu2+), including quantitative comparisons to metalloporphyrin catalysts
4. Oxo transfer from high-valent totally inorganic oxometalloporphyrin analogs, [Xn+W11O39CrVO](9-n)- (Xn+ = P5+, Si4+), to hydrocarbons
5. Highly Active Manganese-Containing Polyoxometalate as Catalyst for Epoxidation of Alkenes with Hydrogen Peroxide
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