Investigation of Structural, Magnetic and Electrical Properties of Chromium Substituted Nickel Ceramic Nanopowders

Author:

Sridhar Rapolu,Ravinder D.,Laxman Naik J.,Vijaya Kumar K.,Maramu N.,Katlakunta S.

Abstract

Nano-ceramic of NiCrxFe2-xO4 (0.1 ≤ x ≤ 1.0) ferrites were synthesized by citrate-gel auto combustion method. The structural parameter such as lattice parameter, X-ray density, bulk density and porosity variations with Cr doping were studied. The average crystallite size is in the range 8.5–10.5 nm. The surface morphology and elemental analysis was studied with SEM (EDAX) spectrum and the structural information analyzed with FTIR spectra. Magnetic properties were discussed with Cr3+ion concentration. Electrical parameters like dc resistivity and drift mobility were reported with function of temperature and dopent concentration from room temperature to well beyond Curie temperature and explained with hopping mechanism between Fe2+↔Fe3+ ions. The activation energies in ferri and para magnetic regions were investigated. Dielectric parameters like dielectric constant, dielectric loss and ac conductivity were investigated variation with frequency and composition.

Publisher

IntechOpen

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