Effect of Laminar Flow on the Corrosion Activity of AA6061-T6 in Seawater

Abstract

The electrochemical behaviour and surface changes on AA6061-T6 alloy exposed to Caribbean seawater from the Cozumel Channel for 30 days under laminar flow (0.1 ms−1) were studied, these contrasting then with stationary conditions. Open circuit potential monitoring and electrochemical current fluctuations, considered as electrochemical noise (EN), were employed as two nondestructive methods. The calculated corrosion current, based on Rn, was one order higher in laminar flow. The fluctuations of current were transformed in the frequency domain. Their power spectral density (PSD) plots were obtained in order to gain information concerning the dynamic of the spontaneous release of energy during the corrosion process. The value of the exponent β in PSD graphs suggested that the localised corrosion on AA6061-T6 surface occurs as a persistent stationary process, which dynamic is controlled by oxygen diffusion. The changes in the morphology and elemental composition of the formed layers revealed that the localised attacks occurred in the vicinity of intermetallic particles rich in Fe and Cu, which act as cathodes.