Submarine Stratovolcano Peperite Syn-Formational Alteration - A Case Study of the Oligocene Smrekovec Volcanic Complex, Slovenia

Abstract

The Oligocene Smrekovec Volcanic Complex is a remnant of a submarine composite stratovolcano with a complex succession of lavas, autoclastic, pyroclastic, syn-eruptive resedimented volcaniclastic and siliciclastic deposits was a favourable environment for the development of peperites. Despite very complex alteration related to the stratovolcano-hosted hydrothermal system with a deep igneous source, locally elevated geothermal gradients and superimposed hydrothermal/geothermal regimes controlled by the emplacement of a shallow intrusive body, authigenic minerals in peperites - particularly pumpellyite and actinolite - show higher temperature stability ranges than those in the underlying and overlying volcanic deposits irrespectively of their lithofacies, porosity and permeability. The formation of authigenic minerals in peperites, such as laumontite, pumpellyite, epidote, prehnite or actinolite, was apparently controlled by ephemeral and localised high-temperature regimes originating from the parent lava flow. Heated pore waters in the host sediment that could have undergone local mixing with deuteric fluids circulated in peperites until thermal gradients persisted, and were the cause of alteration of juvenile clasts and the mingling sediment. The development of pumpellyite required a suitable precursor - fine-grained volcanic ash.