Abstract
Cellulose is the most abundant natural compound in nature and the main component of the cell wall of plants. It is a linear polymer with a high degree of polymerization, responsible for most of the properties of wood. Colloidal phenomena are often used in various industrial production processes. Suspended cellulose, used worldwide in the paper and cellulose industries, with regard to stability, has a high tendency to aggregate and form clots. The different interactions between the dispersed phase and the dispersion phase are one of the critical points in the study of the behavior and stability of colloids. Cellulose is no different, as several studies seek to improve the colloidal stability of cellulose in aqueous media by observing the specific characteristics of the colloid, such as its geometry, mass and area/volume ratio, and the possible interactions between particles that make up the cellulose dispersion in order to understand and control colloidal stability. Therefore, the objective of this chapter is to define the main characteristics of colloids, to classify them, to present the main methods of preparation, to address important aspects about colloid stability and the colloidal stability of cellulose.
Reference26 articles.
1. PANDOCHI, L. “Estudo do Comportamento Coloidal de Suspensão de Fibra de Celulose, Carbonato de Cálcio, Amido Catiônico: Variação da Força Iônica e do pH.” [thesis]. Araraquara: Paulista State University; 2009.
2. MILANEZ, D. H.; AMARAL, R. M.; FARIA, L. I. L.; GREGOLIN, J. A. R. Assessing nanocellulose developments using science and technology indicators. Materials Research, vol. 16, V. 3, pp. 635-641, 2013.
3. BECK, S.; BOUCHARD, J.; BERRY, R. Dispersibility in water of dried nanocrystalline cellulose. Biomacromolecules, vol. 12, pp. 1486-1494, 2012.
4. SHAW, D. J. Introdução à Química dos Colóides e de Superfícies; Edgard Blucher: São Paulo, SP, 1975.
5. LEGRAND, C.P., LAFUMA, F., AUDEBERT, R., “Rheological behavior of colloidal dispersions of hydrophobic particles stabilised in water by amphiphilic polyelectrolytes”, Colloids and Surfaces A, v. 152, pp. 251-261, 1999.