Environmental Evaluation of Surfactant: Case Study in Sediment of Tigris River, Iraq

Abstract

Many chemical pollutants take their way into different environment ecosystems. One of these pollutants is detergent, which these compounds used widely worldwide. There is less attention to their impact on the Iraqi environment, especially on an aquatic system; most of these compounds discharged into the river directly by non-urban communities, in addition to household uses that it had spent throughout the domestic drainage systems. Tigris river is the primary source of water in Baghdad City, Iraq, and passes throughout Baghdad city north to south of the city. This chapter deal with the qualitative and quantitative of these compounds in the sediment as it’s considered the sink of most pollutant compounds. The four sampling sites were chosen along the river for 13 months, starting from Feb 2017 to Feb 2018 and represent as dry and wet seasons. Physicochemical parameters had measured during this study. For the sediment sample, two methods used Photolab and HPLC. The two types of surfactants were extracted from the sediment as follows anionic and nonionic surfactants which they had found at all the study sites, especially in some locations in the midstream. For temporal variation, the dry seasons noticed a high concentration for nonionic surfactant (56.19 and 467.3 μg/g) by Photolab and HPLC, respectively, and for anionic surfactant (135.74 μg/g) by HPLC. In contrast, by Photolab, only anionic surfactant was recorded a high concentration in wet seasons (72.05 μg/g). The lowest frequency of anionic and nonionic was recorded in wet seasons by Photolab and HPLC, respectively (41.83 μg/g and not detectable) unless for NS by HPLC in the dry season (10.80 μg/g). For spatial variation which according to the cluster diagram, the highest concentration for anionic and nonionic surfactants by Photolab had recorded (57.88 and 34.32 μg/g, respectively) at site1, while for HPLC anionic and nonionic surfactants was recorded highest values (48.37 and 235.79, respectively) at site 4. From this study concluded that sites 1 and 4 are the most pollutant than other sites because the activity of discharge of pollution.