Abstract
In dilute solution,
pyridine-2-aldehyde-2'-pyridylhydrazone can behave as a diacid base or as a
tridentate chelating agent. Its cationic bis complexes further undergo two
stages of deprotonation. Equilibrium constants have
been measured at seven temperatures from 5� to 60� and over a range of ionic
strength. They have been used to derive values of enthalpies and entropies of
reaction with H+, Fe2+,
and Zn2+.
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