Author:
Cambie RC,Leong SH,Palmer BD,Preston AF
Abstract
8α,13-Epoxylabd-14-en-2-one
(2-oxomanoyl oxide) (1) has been converted into 3β-hydroxy-13,14,15,16-tetranorlabd-8(17)-en-12-oic
acid (7), a compound with potential as an optically active intermediate for
synthesis. Attempts to couple the acid (7) electrolytically to form α-onocerin
are reported. Coupling of 2-methylenecyclohexylacetic acid (40) gives the dimer
1,2-bis(2-methyl-enecyclohexyl)ethane (43) in 45% yield.
Cited by
8 articles.
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