Abstract
The complexes (C6F5In,L
[L = pyridine (py), Ph3P, Ph3PO, Ph3AsO, or
N,N,N?,N'-tetramethylethylenediamine
(tmed)], (CeF5)31n(OSMe2)2,
and [(C6F5)3)aIn]2bipy (bipy =
2,2'-bipyridyl) have been prepared by reaction of (C6F5)3In,diox
(diox = 1,4-dioxan) with the appropriate ligands, and
(C6F5)31n,AsPh3,( C6F5)3
(THF)2 (THF = tetrahydrofuran), and (C6F5)31n]2(Ph2PCH2)2
have been similarly obtained from (C6F5)3In,OEt2.
Monomeric structures with four-coordinate indium are proposed for the complexes
(C6F5)3In,L (L = py, Ph3P, Ph3As,
Ph3PO,or Ph3AsO), and monomeric five-coordinate
structures for the complexes (C6F5)31n(L)2
(L = Me2SO or
THF). The derivatives [(C6F5)31n]2L
[L = bipy or (Ph2PCH2)2]
and (C6F5)3In,tmed
are considered to have bridging ligands with four- and five- coordinate indium
respectively.
Cited by
18 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献