Abstract
The equilibria
represented by the following equations:
(See diagram in paper)
have been studied in
anhydrous dimethyl sulphoxide at various chloride ion
concentrations. The mechanisms of the reactions are interpreted as dissociative
and this assignment is consistent with the radiochloride
exchange data. The kinetic and equilibria results are
dependent on ion association which is separately treated by conductance
measurements in the case of cis-[CrCl2 en2]+Cl-.
Activation energies are recorded.
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