Author:
Della EW,Reimerink MP,Wright BG
Abstract
The products of
electrophilic addition of mercuric acetate, chromyl chloride and nitrosyl
chloride to 1-chloronorbornene (4) have been investigated. While the rate of
addition is slower than that of norbornene, the magnitude of the directive
effect of the chlorine is found to vary significantly from case to case. Thus
high regiospecificity is observed in oxymercuration-demercuration, moderate
regiospecificity in the addition of nitrosyl chloride, and only minor
preference of attachment in chromyl chloride oxidation. High stereospecificity
is noted in all cases.
Cited by
2 articles.
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