Author:
van den Bergen A,Murray KS,O'Connor MJ,Rehak N,West BO
Abstract
Complexes of iron(111) and
N-substituted salicylaldimines have been prepared of
general formulae Fe(sal-NR)3,? Fe(sal-NR)2 sal, FeCl3(salH-NR)2,
Fe(sal-NR)2X (X = Cl, Br), and [Fe(sal-NR)2]2O. The complexes all show
spin-free magnetic behaviour with moments at room temperature of the order of
5.9 B.M. except for the oxygen-bridged complexes which have low moments (c.2
B.M.) believed due to a spin-exchange process. The infrared spectra and mass
spectra of the complexes are discussed.
Cited by
35 articles.
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