Abstract
The relative rates of the
concurrent A1 and A2 hydrolyses of t-butyl acetate have been measured as a
function of solvent composition in water-dimethyl sulphoxide (DMSO) mixtures. A
large difference in solvent effect is observed, which correlates well with observed
solvent effects on ethyl acetate (A2) and acetal (Al) hydrolyses in the same
solvent system. Activity coefficients have been measured for t-butyl acetate,
ethyl acetate, and acetal in various water-DMSO mixtures.
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