Abstract
In support of earlier work by Okuda, the
apparently homogeneous product from reaction of 2-picoline N-oxide with acetic
anhydride, described in the literature as 2-acetoxymethylpyridine, is shown to
consist of about 66% of this substance, together with approximately equal
amounts of 3-acetoxy-2-picoline and 5-acetoxy-2-picoline. The N.M.R. and mass
spectra of these isomeric acetoxy compounds are discussed.
Cited by
27 articles.
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1. Pyridinols and Pyridones;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
2. Pyridine-1-Oxides;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
3. Part A. Properties and Reactions of Pyridines;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
4. Pyridine and Pyridine Derivatives;Ullmann's Encyclopedia of Industrial Chemistry;2000-06-15
5. (α-Pyridyl) methyl phosphoro-bis-triazolide as a new phosphorylating reagent for internucleotide bond formation;Journal of Biosciences;1988-06