199Hg-1H Spin-spin coupling in vinyl and ethynyl mercurials

Author:

Wells PR,Kitching W

Abstract

The proton magnetic spectra of cis and trans-2-chlorovinylmercuric chloride, bis(trans-2-chlorovinyl)mercury, and methylethynylmercury have been determined. Large variations in the 199Hg-1H spin-spin coupling constants are observed for different hybridization states and different geometries.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 22 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. A brief history of organometallic chemistry in Australia and New Zealand;Applied Organometallic Chemistry;1990-09

2. Organolanthanoids. XII. Reactions of bis(cyclopentadienyl)ytterbium(II) with some diorganomercurials;Inorganica Chimica Acta;1988-02

3. Hg Mercury;Organometallic Compounds of Zinc, Cadmium and Mercury;1985

4. Retention of geometric configuration of the carbon in the reaction of bis(?-chlorovinyl)mercury with ytterbium;Bulletin of the Academy of Sciences of the USSR Division of Chemical Science;1984-02

5. Study of organomercury compounds by high-resolution NMR. VII. ?-chlorovinyl derivatives of mercury;Journal of Structural Chemistry;1983

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