Abstract
E.m.f. measurements of the
cell
���������������������� Pt|H2|HBr(m),
ButOH(X), water|AgBr|Ag
have been made at 298.15 K
for solvent compositions X = 10, 20, 30, 40, 50 and 70% (w/w) of t-butyl
alcohol. These have been used to evaluate the standard potential of the
silver-silver bromide electrode and the free energy of transfer, ΔG�t,
of the acid from water to the respective solvent media. These ΔG�t
values, along with those for hydrochloric acid, are briefly discussed in
relation to ion solvation. ��� Mean ionic activity coefficients of
hydrobromic acid in the various solvents have also been calculated.
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