Abstract
The magnetic susceptibility
in the temperature range 80-400 K is reported for copper(II) complexes of the
general formula CuLX, where L is benzimidazole substituted in the 2-position by
α- or β-hydroxyalkyl groups and in some cases also in the N-position
by a methyl group and X is Br-, Cl-, or acetate. The
magnetic behaviour of 1-(benzimidazol-2- yl)alkanolato complexes is interpreted
in terms of antiferro- magnetically exchange-coupled pairs of copper atoms. The
2- (benzimidazol-2-yl)-alkanolato complex is a linear antiferromagnet.
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