Abstract
A series of 17 compounds
which ignite and explode upon heating have been synthesized. Ignition temperatures
range from 122�
to 261�.
The ability of these compounds to sensitize the primary explosive lead azide to
stab initiation has been determined on 1 : 10 admixtures.
The general trend observed was that stab initiation energies increase with
sensitizer ignition temperature but the overall correlation is poor. An
assessment of the dependence of the ratio of sensitizer to lead azide on stab initiation
energies is also included for two of the compounds. The results are interpreted
in terms of possible mechanisms for the initiation process and support the
hypothesis that frictional processes
are
of primary importance.
Cited by
43 articles.
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