The mass spectra of some simple mixed alkyl, aryl, halo, secondary and tertiary phosphines, arsines and stibines

Author:

Henrick K,Mickiewicz M,Roberts N,Shewchuk E,Wild SB

Abstract

A comparative investigation of the mass spectra of the compounds Me2PhE, MePh2E, MeEtPhE (where E = P, As or Sb), PhPriEH (where E = N, P or As), MePhAsH, MePhEX (where X = Cl or I and E = As; X = Br and E = Sb) and PhPriEX (where X = Cl and E = P or As) has been undertaken at 70 eV. The main fragmentation pathways have been determined and the criteria established for the interpretation of spectra of these simple derivatives applied to a series of more complex arsines.

Publisher

CSIRO Publishing

Subject

General Chemistry

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