Cerium tetrafluoride. II. The system cerium tetrafluoride-cerium trifluoride

Author:

Asker WJ,Wylie AW

Abstract

A tentative phase diagram has been proposed which shows that the system CeF4-CeF3 is essentially eutectic in character. There is no solid solution in the terminal phases. The melting behaviour of the tetrafluoride is complicated by its volatility and by its decomposition into a fluorine-rich vapour and a fluorine-poor liquid. Clarification of phase relationships requires that the system be regarded as portion of the system CeF3-F2.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. X‐ray diffraction, differential scanning calorimetry and evolved gas analysis of aged plutonium tetrafluoride (PuF4);Journal of Radioanalytical and Nuclear Chemistry;2021-06-23

2. Cerium Tetrafluoride: Sublimation, Thermolysis, and Atomic Fluorine Migration;The Journal of Physical Chemistry A;2015-07-28

3. New multicomponent fluoride glasses;Journal of Materials Science;1996-06

4. Cerium Tetrafluoride. I. Preparation and reactions;Australian Journal of Chemistry;1965

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