Author:
Krankovits EM,Magee RJ,O'Conner MJ
Abstract
The preparation of a number
of polymeric, octahedral bis(N- alkylmonothiocarbamato)nickel(II)
complexes and some of their base adducts is described. ��� The preparation and characterization of
some bis(phosphine)bis(N- alkylmono-thiocarbamato)palladium(II)
compounds are also described for the first time. The butyl compound is monomeric
in chloroform and infrared spectral measurements of all compounds indicate that
the monothiocarbamate ligands are bonded to palladium through the sulphur atoms
only. The proton magnetic resonance spectrum of the dimethylphenylphosphine
complex shows clearly that the phosphine groups are trans in the complexes. ��� Simple bis(monothiocarbamato)-palladium(II)
or -platinum(II) have not been isolated but pyrrolidinium tetra(N- pyrrolidylmonothiocarbamato)-palladium(II) or -platinum(II)
compounds are formed. Infrared measurements indicate that the mono-thiocarbamate
ligands are bonded to the metal through both oxygen and sulphur atoms but no
definite structure can be proposed for these compounds at present.
Cited by
27 articles.
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cis
‐Pt
II
(phos)
2
Moieties (phos = PPh
3
or ${1 \over 2}$dppe), Cyclometallation vs. Hydrolysis to Monothiocarbamato, and the Crystal Structure of
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‐Bis(
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‐dimethylmonothiocarbamato)bis(triphenylphosphane)platinum(
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