Abstract
Six 4,5-di-X-9,l0-dihydrophenanthrenes (X = H, F, OCH3, Cl, CH3, CF3) were synthesized and their inversion rates were investigated by n.m.r., spectroscopy. The barriers to inversion at a standard temperature (∆G‡;340) ranged from <25 to >120 kJ mol-l and showed good correlation with the van der Waals radii of the interacting substituents at C4 and C5 and with the previously proposed 'apparent overlap' parameter.
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43 articles.
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