Author:
Baba Gnon,Guillemin Jean-Claude
Abstract
Functionalised 1-alkynylarsines were synthesised by reaction of the corresponding 1-alkynyltributylstannane on arsenic trichloride followed by chemoselective reduction of the formed 1-alkynyldichloroarsine by tributyltin hydride in the presence of small amounts of a radical inhibitor. Rearrangements of these compounds into the corresponding arsaalkynes were attempted.
Cited by
1 articles.
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1. Roger F. C. Brown Memorial Issue;Australian Journal of Chemistry;2014