Abstract
The position of the equilibria between aldohexoses
and 3-deoxyaldohexoses and their 1,6-anhydrides, and
between heptuloses and their 2,7-anhydrides, has been
determined by gas chromatography. The results are in good agreement with data
calculated from conformational interaction energies. D-Talose
gives equal amounts of the 1,6-anhydropyranose and
the 1,6-anhydrofuranose. D-glycero-D-gulo-Heptose
gives 66% of the 1,7- and
only 9% of the 1,6-anhydride.
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