Abstract
Complex nickel(II)
nitrites, NiLn(NO2)2, can be prepared in good
yield by the reaction of amines with K4Ni(NO2)6.
Bonding of the NO2 group depends on the nature of the amine.
Paramagnetic, octahedral complexes of propane-1,3-diamine (pn)
and some of its N-alkyl derivatives were: pn, n = 2,
dinitro; N-methyl derivative, n = 2, dinitrito; N-ethyl, n = 2, dinitrito;
N,N-dimethyl, n = 1, dinitrito with bidentate nitrito groups. Corresponding
thiocyanate complexes were all NiL2(NCS)2. Homopiperazine
gave diamagnetic, square-planar complexes, NiL22+, for
all anions examined.
Cited by
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