Some studies in inorganic complexes. IV. Titanium(III) and Titanium(IV)

Author:

Sutton GJ

Abstract

The titanium complexes TiCl3.D.H2O, TiBr3.D.H2O, TiCl4.D, and TiBr4.D, In which D is o-phenylenebisdimethylarsine. have been prepared and studied. By means of conductivity and molecular weight measurements, it has been shown that they are 6-covalent non-electrolytes. The thiocyanato complexes [NH4][Ti(SCN)4(H2O)2,], [NH4][Ti(SCN)4], and [NH4][Ti(SCN)4OH.H2O] were also prepared and their structures verified by conductivity measurements.

Publisher

CSIRO Publishing

Subject

General Chemistry

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