Abstract
The magnetic susceptibility
and anisotropy of the hexagonal salt Cs2UCl6 were
measured from 80 to 300 K and found to be essentially independent of
temperature. The results were interpreted using a parameterized crystal field
model. k was found to be 0.93, but
the L C3-U-Cl deduced does not agree with the value known from the
structure for any reasonable range of the crystal field parameter p2.
It is deduced that the next state, T4(Oh), above the ground T1 state should be
split by 50 cm-l. This is in fair agreement with the value observed
from the spectrum, 82 cm-1.
Cited by
2 articles.
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