'Pseudo-star' Copolymers Formed by a Combination of RAFT Polymerization and Isocyanate-Coupling-Reference-Cited by-同舟云学术

'Pseudo-star' Copolymers Formed by a Combination of RAFT Polymerization and Isocyanate-Coupling

Published:2011 Issue:8 Volume:64 Page:1047
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Moraes John,Maschmeyer Thomas,Perrier Sébastien

Abstract

We describe the formation of pseudo-star copolymers via incorporation of an isocyanate-bearing monomer, dimethyl meta-isopropenyl benzyl isocyanate (TMI) into a homopolymer of butyl acrylate (BA) using a one-pot, two-step synthesis. The resultant product maintains the functionality of the isocyanate moiety, which is used to attach poly(ethylene glycol) methyl ether onto the copolymeric chain under benign reaction conditions. The resultant pseudo-star copolymers were isolated and their self-assembly in the presence of water studied.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

https://www.publish.csiro.au/CH/pdf/CH11133

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