Abstract
The solvolysis of aromatic sulphonyl
chlorides in methanol-acetone and ethanol-acetone shows only small, irregular
effects due to para-substituents because the experimental temperature range is
close to the isokinetic temperature. The modification of reaction conditions in
SN2 substitutions, so that
the isokinetic condition is brought into the experimental temperature range, is
discussed.
Rates for methanolysis are lower than
those for hydrolysis and are about four times the rates for the corresponding
ethanolysis reactions.
Cited by
24 articles.
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