Abstract
Rhodium- catalysed hydroformylation of readily available ortho-propenylanilines gives 4,5- dihydro-3H-1-benzazepines together with small amounts of substituted 3-methylquinolines (≤15%). The regioselectivity of these reactions and the hydroformylation of related ortho-propenylphenols are discussed.
Cited by
36 articles.
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1. Irpeksins A–E, 1,10-seco-Eburicane-Type Triterpenoids from the Medicinal Fungus Irpex lacteus and Their Anti-NO Activity;Journal of Natural Products;2018-10-08
2. Stereoselective Synthesis of Novel 2-Alkenyl-2,3,4,5-tetrahydro-1,4-epoxy-1-benzazepines and 2-Alkenyl-2,3,4,5-tetrahydro-1H-1-benzazepin-4-ols;Synthesis;2012-11-08
3. ChemInform Abstract: The Stereochemistry of Organometallic Compounds. Part 35. Hydroformylation of ortho-Propenylanilines and ortho-Propenylphenols: A New Route to 4,5-Dihydro-3H-1-benzazepines.;ChemInform;2010-08-22
4. Tautomeric Equilibria and Rearrangements Involving Phenols;PATAI'S Chemistry of Functional Groups;2009-12-15
5. Synthesis and Evaluation of the Cytotoxicities of Neoflavenes;Journal of the Chinese Chemical Society;2008-08