Author:
Bergmann David J.,Campi Eva M.,Jackson W. Roy,Patti Antonio F.
Abstract
Diazabicycloalkanes and oxazabicycloalkanes containing medium and large rings
can be prepared by rhodium-catalysed reactions of
N-alkenylpropane-1,3-diamines and
2-(alkenylamino)ethanols with H2/CO in excellent
yields without the need for high dilution. Selective ring opening of these
compounds can lead to large heterocycles.
Cited by
16 articles.
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