Author:
Johns SR,Lamberton JA,Li CS,Sioumis AA
Abstract
A bisbenzylisoquinoline
and three noraporphine alkaloids have been isolated
from the bark of a Popowia
species (Popowia
cf. cyanocarpa
Laut. 85 K. Schum.) of the
family Annonaceae. The major alkaloid is 1-hydroxy-2,9,10-trimethoxynoraporphine (1), and comparison with the known
alkaloid wilsonirine, to which the same structure had
been assigned, indicates that the Popowia base is the (+)-form, while
wilsonirine is largely racemic.
Another alkaloid, 2-hydroxy-1-methoxynoraporphine
(3), is identical with the known alkaloid asimilobine,
while the third noraporphine, 1-hydroxy-2,10,11-trimethoxynoraporphine (4), has not previously been
reported. The bisbenzylisoquinoline
alkaloid, dauricine O-methyl ether (6), has not
previously been isolated as an alkaloid but it has been prepared as a
derivative of dauricine.
Cited by
28 articles.
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