Abstract
Rate constants and
associated enthalpies and entropies of activation have been determined for
reactions occurring at equilibrium in solutions containing K2CaEDTA
and KαH4-αEDTA,
where x is a stoicheiometric number. The reactions,
which include exchange between the bound ligand in CaEDTA2-
and the various protonated forms of the free ligand
as well as the formation and decomposition reactions of CaEDTA2-
and CaHEDTA-, have been investigated by N.M.R.
techniques using the Job method of continuous variations. Reaction mechanisms
are proposed.
Cited by
15 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献