Abstract
The course of the iodine/lead
tetraacetate oxidation of the four alcohols laurenan-2β-ol(2),
laurenan-2α-ol (3), 1βH-laurenan-2β-ol (4) and
1βH-laurenan-2α-ol (5) is described. Structural assignments have been
made with the aid of 13C n.m.r. after ether ring opening and
conversion into derivatives of lauren-1-ene (1). Where possible, the results of
remote functionalization have been used to infer the preferred molecular
conformation.
Cited by
13 articles.
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