Photocatalysis with TiO2 Applied to Organic Synthesis

Abstract

Titanium dioxide is a versatile heterogeneous catalyst. Absorption of light by a TiO2 particle leads to the formation of an electron–hole pair. Electron transfer from or to the particle induces redox reactions. Although mainly applied in the context of environmental chemistry, these processes are also used to selectively transform organic compounds. Oxidations and reductions have been carried out. Applications to the synthesis of heterocycles have been reported. Many C–C bond formation reactions have been performed. Owing to adsorption of the substrates or by different surface modifications, visible light can be used to excite the catalytic system, which generates mild reaction conditions.