Abstract
Reaction of manool and its
derivatives with ozone gave stable ozonides. The structure (6) of one of the
ozonides isolated is of striking similarity to the perfumery acetals (1) and
(2) derived from the potassium permanganate oxidation of manool (3). Another
compound 8β,13:8,14-diepoxy-15,17-dinorlabdan-14β-ol(7) was isolated
as the major ozonolysis product and is a precursor of the lactone perfume (10).
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