Abstract
The following complexes of the chelating
ligands 2-methyl-6-aminomethylpyridine (6-methyl-2-picolylamine or mepic) and
2-thioamidopyridine (thiopic) have been prepared and studied: [Cu mepic2X]X, where X = Cl, Br, I, NO3,
ClO4, [Cu mepic2C2O4],
[Ni mepic3][ClO4]2,
[M(II) thiopic3][ClO4]2,
[M(III) thiopic3][ClO4]3,
(M(II) = Co, Ni; M(III) = CO, Fe), and [Co thiopic3]Cl2. Conductance measurements in ethanol,
nitromethane, and nitrobenzene indicate that the [Cu mepic2X]X
complexes are 5-covalent whilst the other complexes studied are 6-covalent. All
the complexes are "spin free" excepting those of Co(III). Absorption
spectra of the copper complexes in the near ultraviolet region were also made.
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