Author:
Canty AJ,Kishimoto R,Tyson RK
Abstract
The complexes RSHgX (R = Et, But; X = Cl,
Br) may be prepared by reaction of the alkanethiol with HgX2 in
ethanol, and the 2- methylpropane-2-thiolates crystallize from pyridine as (ButSHgCl)2-C5H5N
and ButSHgBr,C5H5N. The complexes RSHgO2CMe
(R = Me, Et) may be prepared by reaction of mercuric acetate with Hg(SR)2
in water, and form crystalline RSHgO2CMe,C5H5N
when dissolved in pyridine. Infrared and Raman spectra indicate coordination of
pyridine in the pyridinates. Mercury-sulfur stretching vibrations of RSHgO2CMe
(R = Me, Et, Pr, Bu) are discussed.
Cited by
12 articles.
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