Author:
Brown RD,Godfrey PD,Winkler DA
Abstract
A high-resolution study of
hyperfine splitting in the microwave spectrum of methanimine
has yielded the following values (in MHz) for 14N hyperfine
constants: xaa- 0.898(8), xbb - 2.693(8), xcc
3.591(8), Ca -0.0495(47), Cb -
0*0097(27), Cc -0.0012(24). The localized theory for calculation of
the magnetic hyperfine constants appears generally to overestimate Cc
by an order of magnitude for molecules structurally similar to methanimine.
Cited by
26 articles.
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