Abstract
Some heteroaromatic
compounds with methyl substituents in the heterocyclic ring, such as
2-methylbenzothiazole, 2-methylbenzoxazole, and analogues, undergo rapid methyl
group chlorination when heated with thionyl chloride. A mechanism for such
reactions is proposed.
Cited by
11 articles.
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1. Thionyl Chloride;Encyclopedia of Reagents for Organic Synthesis;2017-04-11
2. Novel one-pot synthesis of diverse γ,δ-unsaturated β-ketoesters by thermal cascade reactions of diazodicarbonyl compounds and enol ethers: transformation into substituted 3,5-diketoesters;Org. Biomol. Chem.;2014
3. References;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
4. References;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02
5. Alkylquinolines and Arylquinolines;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02