Abstract
The magnetic anisotropy of Mn(antipyrene)6(ClO4)2
below 20 K indicates that the zero-field splitting parameter (D) is about three
times greater than obtained from e.p.r. measurements
of manganese doped into a series of isomorphous host lattices. Shape anisotropy
effects are significant unless spherical crystals are used. The interpretation
of the magnetic anisotropy above 20 K is complicated by the large diamagnetic
contribution from the ligands and it is suggested that there are significant differences
in the orientation of the ligand molecules in the isomorphous manganese and
magnesium complexes.
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