Abstract
The potential energy surfaces for the
decomposition of HCO, CH3CO, and COCl radicals have been constructed
using Bawn's (1938, 1939) method with new parameter values. The values obtained
for the energies of activation for decomposition were of the order of 26, 18,
and 6 kcal mole-1 respectively. The CH3CO and COCl values agree with
experimental estimates and consequently it is believed that the formyl value is
of the correct order of magnitude.
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