Abstract
When ferrocene reacts with varying amounts
of benzoyl peroxide in benzene solution, the iron in ferrocene is almost
completely converted into ferric benzoate. The additional benzoyl peroxide
apparently reacts with the cyclopentadienyl fragments forming benzoic acid and
intractable material.
As neither carbon dioxide nor diphenyl
could be isolated from the reaction mixture, it would appear that ferrocene
acts as an efficient " scavenger " for benzoyloxy radicals.
Cited by
12 articles.
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