Abstract
The
chemical defensive system of the ladybird Cryptolaemus montrouzieri consists mainly of three related alkaloids. Two of these have
been identified as cis-1-(6-methyl-2-piperidyl)propan-2-one (3) and
1-methyl-9-azabicyclo[3,3,1]nonan-3-one (2);
the third is very unstable and readily isomerizes to (3).
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