Abstract
Ethyl N-methyl-N-phenylcarbamate
decomposes in the gas phase over the range 329-380� to give N-methylaniline,
carbon dioxide, and ethylene. The reaction is quantitative, and is first order
in the carbamate. First-order rate constants are described by the equation
������������������� k1 = 1012.44
exp(-45,380/RT) (s-1)
and are unaffected by the
addition of cyclohexene or by increase in the surface to volume ratio of the
reaction vessel. The reaction is considered to be unimolecular and likely to
proceed by means of a mechanism of the type represented by the pyrolyses of
acetates, xanthates, and carbonates.
Cited by
27 articles.
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