Novel Synthesis and Structure of a Bridging Peroxo Pentaaminecobalt(III) Dimer-Reference-Cited by-同舟云学术

Novel Synthesis and Structure of a Bridging Peroxo Pentaaminecobalt(III) Dimer

Published:1986 Issue:9 Volume:39 Page:1331
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Gainsford GJ,Jackson WG,Sargeson AM

Abstract

The addition of excess glycine ethyl ester to Co{(H2NCH2CH2)3N}(OSMe2)23+ in Me2SO leads to the symmetrical dimeric peroxo ion p,p - [Co( tren )(NH2CH2CO2Et)]2O24+ under mild conditions. The single-crystal X- ray structure of the perchlorate salt is described, and the mechanism for the dimer formation is considered.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9861331

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