Reactions of Adamantanethione with Ketenes: Formation of a 1,3,5-Dioxathiane-Reference-Cited by-同舟云学术

Reactions of Adamantanethione with Ketenes: Formation of a 1,3,5-Dioxathiane

Published:2014 Issue:3 Volume:67 Page:525
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Drinnan Nicholas,Wentrup Curt

Abstract

The reaction between adamantanethione 1 and diphenylketene 9 yields 2,4-bis(diphenylmethylidene)-1,3,5-dioxathiane 14 via ketene–thione zwitterions. This is the first example of the formation of a 1,3,5-dioxathiane in a ketene reaction.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH13449

Reference12 articles.

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2. Ketene XXXV: Einwirkung von Diphenylketen auf Thioketone

3. Cycloaddition of Singlet Oxygen and 4‐Methyl‐4 H ‐1,2,4‐triazole‐3,5‐dione to 7‐Adamantylidene‐1,3,5‐cycloheptatriene and Derivatives

4. A phenyl-group participation in the antisymmetric orbital interaction for [8 + 2] cycloaddition of tropothione with diphenylketene

5. Acyl- and Thioacylketenes: Synthesis of 3-Benzoly-4-phenylthiet-2-one

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