Abstract
A number of
bis(phenylethynyl)-substituted anthracenes and naphthacenes have been
synthesized and their suitability as fluorescent additives for peroxyoxalate
chemiluminescence evaluated. Fluorescence and chemiluminescence emission data
for all compounds are presented. Both 2-chloro- and
6-chloro-5,12-bis(phenylethynyl)naphthacene provide effective scarlet
chemiluminescence with the peroxyoxalate system (λmax 609 and
614 nm respectively). Although solutions of both compounds decolorize slowly in
the presence of air and light, when used in concentrations of 1-5 × 10-3M
they allow efficient chemiluminescence for greater than 5 h.
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