Oxidative Dimerisation of Isoflavones: Synthesis of Kudzuisoflavone A and Related Compounds-Reference-Cited by-同舟云学术

Oxidative Dimerisation of Isoflavones: Synthesis of Kudzuisoflavone A and Related Compounds

Published:2012 Issue:10 Volume:65 Page:1377
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Deodhar Mandar,Wood Kasey,Black David StClair,Kumar Naresh

Abstract

Kudzuisoflavone-A was successfully synthesised via oxidative dimerisation of daidzein in the presence of cuprous chloride. Appropriately substituted isoflavones also undergo regioselective oxidative dimerisation when treated with thallium trifluoroacetate to give novel 6′,6′″-biisoflavones in good yield. A rationale for the regioselectivity is proposed.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

https://www.publish.csiro.au/CH/pdf/CH12108

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