Abstract
Evidence is presented for
the structures of the products isolated from the light-induced rearrangement of
benzylenol ethers of Δ4-3-oxo-steroids.
The products obtained on irradiation of benzyl vinyl ether indicate that the
rearrangement proceeds by homolysis of the
benzyl-oxygen bond. Nuclear magnetic
resonance evidence is presented for the existence of an internal phenyl-ketone
interaction in compound (X).
Cited by
27 articles.
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